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Arginine is converted into a molecule called nitric oxide, which causes vasodilation of blood vessels by relaxing the smooth muscle cells that constrict them ( Interestingly, consuming citrulline may increase arginine in the body more than consuming arginine itself ( This is because of differences in how the body processes and absorbs arginine and citrulline ( The increase in nitric oxide and blood flow may be one of the processes involved in citrullines beneficial effects on exercise performance

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Almeida, A., Moncada, S

Huot et al., 1997)