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Altern Ther Health Med 21:2231 Nadeem RI, Ahmed HI, El-Sayeh BM (2018) Protective effect of vinpocetine against neurotoxicity of manganese in adult male rats

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The overwhelming dominance of ROS generated by enzymes like NADPH oxidases and xanthine oxidase over antioxidants like superoxide dismutase causes cell injury and tissue damage through direct injury, lipid peroxidation and protein oxidation leading to protease release and antioxidant and antiprotease enzyme inactivation as well as alteration of transcription factors activator protein-1 and NFB

This reduced interaction is thought to delay the initiation of the circadian repression phase, thereby preventing premature repression, and ensuring proper rhythmicity [100]